全文获取类型
收费全文 | 3198篇 |
免费 | 687篇 |
国内免费 | 599篇 |
专业分类
化学 | 1902篇 |
晶体学 | 15篇 |
力学 | 349篇 |
综合类 | 57篇 |
数学 | 1038篇 |
物理学 | 1123篇 |
出版年
2024年 | 16篇 |
2023年 | 82篇 |
2022年 | 180篇 |
2021年 | 269篇 |
2020年 | 341篇 |
2019年 | 211篇 |
2018年 | 189篇 |
2017年 | 150篇 |
2016年 | 194篇 |
2015年 | 171篇 |
2014年 | 159篇 |
2013年 | 290篇 |
2012年 | 133篇 |
2011年 | 170篇 |
2010年 | 148篇 |
2009年 | 199篇 |
2008年 | 185篇 |
2007年 | 179篇 |
2006年 | 178篇 |
2005年 | 115篇 |
2004年 | 148篇 |
2003年 | 115篇 |
2002年 | 105篇 |
2001年 | 70篇 |
2000年 | 67篇 |
1999年 | 71篇 |
1998年 | 52篇 |
1997年 | 44篇 |
1996年 | 32篇 |
1995年 | 35篇 |
1994年 | 21篇 |
1993年 | 17篇 |
1992年 | 12篇 |
1991年 | 17篇 |
1990年 | 14篇 |
1989年 | 9篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1985年 | 23篇 |
1984年 | 16篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1981年 | 10篇 |
1980年 | 6篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1977年 | 5篇 |
1975年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有4484条查询结果,搜索用时 31 毫秒
91.
Lei Sun Jiahui Geng Dr. Mengyou Gao Dr. Dehua Zheng Zhongxin Jing Qingyun Zhao Prof. Jianjian Lin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(42):10998-11004
Fe0.95S1.05 with high reactivity and stability was incorporated into WS2 nanosheets via a one-step solvothermal method for the first time. The resulted hybrid catalyst has much higher catalytic activity than WS2 and Fe0.95S1.05 alone, and the optimal WS2/Fe0.95S1.05 hybrid catalyst was found by adjusting the feed ratio. The addition of Fe0.95S1.05 was proven to be able to enhance the hydrogen evolution reaction (HER) activity of WS2, and vice versa. At the same time, it was found that the catalytic effect of the hybrid catalyst was the best when the feed ratio was W : Fe=2 : 1. In other words, we confirmed that there is a synergistic effect between W- and Fe-based sulfide hybrid catalysts, and validated that the reason for the improved HER performance is the strong interaction between the two in the middle sulfur. WS2/Fe0.95S1.05-2 hybrid catalyst leads to enhanced HER activity, which shows a low overpotential of ∼0.172 V at 10 mA cm−2, low Tafel slope of ∼53.47 mV/decade. This study supplies innovative synthesis of a highly active WS2/Fe0.95S1.05 hybrid catalyst for HER. 相似文献
92.
93.
The migration of a downsized crescent-shaped dune was investigated in a wind tunnel experiment.Quantified upwind influx and vertical oscillation of the sand bed were introduced to modulate the saturation level of the sand flux above the dune surface to affect dune evolution.The evolution was recorded by top-view photography and then abstracted as the evolution of self-defined characteristic quantities using a digital image processing algorithm.The results showed that,in contrast to the case for spanwise quantities,the evolution of streamwise quantities corresponds to a linear increase in the modulation magnitude more positively and in a monotonic and convergent manner.In contrast with quantities on the windward face,the changes in quantities with respect to the horns were nonmonotonic with time and almost uncorrelated with the variation in modulation strength,which reveals the distinctiveness of leeside evolution. 相似文献
94.
Hanwen Ning 《Applicable analysis》2013,92(4):563-577
In this article, we consider dynamic behaviours of a class of non-linear delay stochastic evolution equations. Local existence and uniqueness of the solutions are obtained with the aid of proper iterative scheme and moment estimations. We also propose a continuation result and our results generalize the known results. 相似文献
95.
Dr. Tana Koudelakova Dr. Radka Chaloupkova Dr. Jan Brezovsky Dr. Zbynek Prokop Dr. Eva Sebestova Dr. Martin Hesseler Dr. Morteza Khabiri Maryia Plevaka Daryna Kulik Dr. Ivana Kuta Smatanova Dr. Pavlina Rezacova Dr. Rudiger Ettrich Prof. Uwe T. Bornscheuer Prof. Jiri Damborsky 《Angewandte Chemie (International ed. in English)》2013,52(7):1959-1963
96.
Xin Chen Aleksandra M. Krajewska Dr. Cormac McGuinness Amy Lynes David McAteer Nina Berner Prof. Georg Duesberg Prof. Jonathan N. Coleman Prof. Aidan R. McDonald 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(3):984-992
Covalently tethering photosensitizers to catalytically active 1T-MoS2 surfaces holds great promise for the solar-driven hydrogen evolution reaction (HER). Herein, we report the preparation of two new RuII-complex-functionalized MoS2 hybrids [RuII(bpy)2(phen)]-MoS2 and [RuII(bpy)2(py)Cl]-MoS2. The influence of covalent functionalization of chemically exfoliated 1T-MoS2 with coordinating ligands and RuII complexes on the HER activity and photo-electrochemical performance of this dye-sensitized system was studied systematically. We find that the photo-electrochemical performance of this RuII-complex-sensitized MoS2 system is highly dependent on the surface extent of photosensitizers and the catalytic activity of functionalized MoS2. The latter was strongly affected by the number and the kind of functional groups. Our results underline the tunability of the photovoltage generation in this dye-sensitized MoS2 system by manipulation of the surface functionalities, which provides a practical guidance for smart design of future dye-sensitized MoS2 hydrogen production devices towards improved the photofuel conversion efficiency. 相似文献
97.
This paper assesses the forecasting performance of count data models applied to arts attendance. We estimate participation models for two artistic activities that differ in their degree of popularity – museums and jazz concerts – with data derived from the 2002 release of the Survey of Public Participation in the Arts for the United States. We estimate a finite mixture model – a zero-inflated negative binomial model – that allows us to distinguish between “true” non-attendants and “goers” and their respective behaviour regarding participation in the arts. We evaluate the predictive (in-sample) and forecasting (out-of-sample) accuracy of the estimated model using bootstrapping techniques to compute the Brier score. Overall, the results indicate the model performs well in terms of forecasting. Finally, we draw certain policy implications from the model’s forecasting capacity, thereby allowing the identification of target populations. 相似文献
98.
Elisa Musella Dr. Isacco Gualandi Dr. Erika Scavetta Dr. Massimo Gazzano Arianna Rivalta Dr. Elisabetta Venuti Dr. Meganne Christian Dr. Vittorio Morandi Prof. Dr. Domenica Tonelli 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(71):16301-16310
Layered double hydroxides (LDHs) have been widely studied for their plethora of fascinating features and applications. The potentiostatic electrodeposition of LDHs has been extensively applied in the literature as a fast and direct method to substitute classical chemical routes. However, the electrochemical approach does not usually allow for a fine control of the MII/MIII ratio in the synthesized material. By employing a recently proposed potentiodynamic method, LDH films of controlled composition are herein prepared with good reproducibility, using different ratios of the trivalent (Fe or Al) to bivalent (Co) cations in the electrolytic solution. All the obtained materials are shown to be effective oxygen evolution reaction (OER) catalysts, and are thoroughly characterized by a multi-technique approach, including FE-SEM, XRD, Raman, AES and a wide range of electrochemical procedures. 相似文献
99.
Zenghui Yang Fuzhi Song Qihua Wang Tingmei Wang 《Journal of polymer science. Part A, Polymer chemistry》2016,54(24):3858-3867
In this work, two kinds of high temperature shape memory copolyimides were prepared and the shape memory cycles induced structural evolution of macromolecular chains was investigated in detail. The glass transition temperature (Tg) of poly(benzoxazole‐co‐imide) (PI1) and poly(benzimidazole‐co‐imide) (PI2) are 280 °C and 355 °C, respectively. The results show that PI1 could keep stable macromolecular chain structure under shape memory cycles and exhibit outstanding shape memory performance (Rf > 98%, Rr > 97%) under different stretch condition. Whereas, shape memory cycles induced orientation with more ordered macromolecular chains packing is formed for PI2 after several thermal mechanical cycles, which strongly affect physical crosslinking points, thermal mechanical properties as well as shape memory behaviors. The study on macroscopic property and microscopic structure evolution will promote a better understanding of the shape memory effect of polyimides and accelerate development of high performance polyimides for shape memory applications. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 3858–3867 相似文献
100.
Hydrogen peroxide activated by boric acid in the presence of sulfuric acid has been shown to be an efficient oxidizing system for direct conversion of aromatic aldehydes and ketones to phenols. 相似文献